Besides the fact that each card-template can have it's own unique printer connected, via the Windows Printers functionality, you can make specific Windows printers available to overrule the default card-template printer which you configure in the Printer Options section.
When the Windows Printer Manager window is opened, you can make the printer available by checking the check box in the list view. You can also move printers up and down and rename them so they have more user friendly names.
The selected printers will become available in Windows Printers tab under the explorer menu.